1
AIEEE 2008
MCQ (Single Correct Answer)
+4
-1
At 80oC, the vapour pressure of pure liquid ‘A’ is 520 mm Hg and that of pure liquid ‘B’ is 1000 mm Hg. If a mixture solution of ‘A’ and ‘B’ boils at 80oC and 1 atm pressure, the amount of ‘A’ in the mixture is (1 atm = 760 mm Hg)
A
52 mol percent
B
34 mol percent
C
48 mol percent
D
50 mol percent
2
AIEEE 2008
MCQ (Single Correct Answer)
+4
-1
Which of the following pair of species have the same bond order?
A
CN- and NO+
B
CN- and CN+
C
$$O_2^-$$ and CN-
D
NO+ and CN+
3
AIEEE 2008
MCQ (Single Correct Answer)
+4
-1
The bond dissociation energy of B - F in BF3 is 646 kJ mol-1 whereas that of C - F in CF4 is 515 kj mol-1. The correct reason for higher B - F bond dissociation energy as compared to that of C - F is
A
stronger $$\sigma$$ bond between B and F in BF3 as compared to that between C and F in CF4
B
significant $$p\pi - p\pi$$ interaction between B and F in BF3 whereas there is no possibility of such interaction between C and F in CF4
C
lower degree of $$p\pi - p\pi$$ interaction between B and F in BF3 than that between C and F in CF4
D
smaller size of B - atom as compared to that of C- atom.
4
AIEEE 2008
MCQ (Single Correct Answer)
+4
-1
The ionization enthalpy of hydrogen atom is 1.312 × 106 J mol−1. The energy required to excite the electron in the atom from n = 1 to n = 2 is
A
8.51 × 105 J mol−1
B
6.56 × 105 J mol−1
C
7.56 × 105 J mol−1
D
9.84 × 105 J mol−1
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