1
AIEEE 2008
MCQ (Single Correct Answer)
+4
-1
Which one of the following constitutes a group of the isoelectronic species?
A
$$C_2^{2 - }$$, $$O_2^{-}$$, CO, NO
B
$$NO^{+}$$, $$C_2^{2 - }$$, CN-, $$N_2$$
C
CN-, $$N_2$$, $$O_2^{2-}$$, $$C_2^{2 - }$$
D
$$N_2$$, $$O_2^{-}$$, $$NO^{+}$$, CO
2
AIEEE 2008
MCQ (Single Correct Answer)
+4
-1
The ionization enthalpy of hydrogen atom is 1.312 × 106 J mol−1. The energy required to excite the electron in the atom from n = 1 to n = 2 is
A
8.51 × 105 J mol−1
B
6.56 × 105 J mol−1
C
7.56 × 105 J mol−1
D
9.84 × 105 J mol−1
3
AIEEE 2008
MCQ (Single Correct Answer)
+4
-1
The bond dissociation energy of B - F in BF3 is 646 kJ mol-1 whereas that of C - F in CF4 is 515 kj mol-1. The correct reason for higher B - F bond dissociation energy as compared to that of C - F is
A
stronger $$\sigma$$ bond between B and F in BF3 as compared to that between C and F in CF4
B
significant $$p\pi - p\pi$$ interaction between B and F in BF3 whereas there is no possibility of such interaction between C and F in CF4
C
lower degree of $$p\pi - p\pi$$ interaction between B and F in BF3 than that between C and F in CF4
D
smaller size of B - atom as compared to that of C- atom.
4
AIEEE 2008
MCQ (Single Correct Answer)
+4
-1
Which of the following pair of species have the same bond order?
A
CN- and NO+
B
CN- and CN+
C
$$O_2^-$$ and CN-
D
NO+ and CN+
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