1
AIEEE 2008
MCQ (Single Correct Answer)
+4
-1
The vapour pressure of water at 20oC is 17.5 mm Hg. If 18 g of glucose (C6H12O6) is added to 178.2 g of water at 20oC, the vapour pressure of the resulting solution will be
A
17.675 mm Hg
B
15.750 mm Hg
C
16.500 mm Hg
D
17.325 mm Hg
2
AIEEE 2008
MCQ (Single Correct Answer)
+4
-1
The bond dissociation energy of B - F in BF3 is 646 kJ mol-1 whereas that of C - F in CF4 is 515 kj mol-1. The correct reason for higher B - F bond dissociation energy as compared to that of C - F is
A
stronger $$\sigma$$ bond between B and F in BF3 as compared to that between C and F in CF4
B
significant $$p\pi - p\pi$$ interaction between B and F in BF3 whereas there is no possibility of such interaction between C and F in CF4
C
lower degree of $$p\pi - p\pi$$ interaction between B and F in BF3 than that between C and F in CF4
D
smaller size of B - atom as compared to that of C- atom.
3
AIEEE 2008
MCQ (Single Correct Answer)
+4
-1
Which of the following pair of species have the same bond order?
A
CN- and NO+
B
CN- and CN+
C
$$O_2^-$$ and CN-
D
NO+ and CN+
4
AIEEE 2008
MCQ (Single Correct Answer)
+4
-1
Which one of the following constitutes a group of the isoelectronic species?
A
$$C_2^{2 - }$$, $$O_2^{-}$$, CO, NO
B
$$NO^{+}$$, $$C_2^{2 - }$$, CN-, $$N_2$$
C
CN-, $$N_2$$, $$O_2^{2-}$$, $$C_2^{2 - }$$
D
$$N_2$$, $$O_2^{-}$$, $$NO^{+}$$, CO

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