1
AIEEE 2007
MCQ (Single Correct Answer)
+4
-1
Consider the reaction, 2A + B $$\to$$ products. When concentration of B alone was doubled, the half-life did not change. When the concentration of A alone was doubled, the rate increased by two times. The unit of rate constant for this reaction is
A
L mol-1 s-1
B
no unit
C
mol L-1 s-1
D
s-1
2
AIEEE 2007
MCQ (Single Correct Answer)
+4
-1
The energies of activation for forward and reverse reactions for A2 + B2 $$\leftrightharpoons$$ 2AB are 180 kJ mol−1 and 200 kJ mol−1 respectively. The presence of catalyst lowers the activation energy of both (forward and reverse) reactions by 100 kJ mol−1. The enthalpy change of the reaction ( A2 + B2 $$\to$$ 2AB) in the presence of catalyst will be (in kJ mol−1)
A
300
B
120
C
200
D
20
3
AIEEE 2007
MCQ (Single Correct Answer)
+4
-1
The cell, Zn | Zn2+ (1M) || Cu2+ (1M) | Cu($$E_{cell}^o$$ = 1.10V) was allowed to be completely discharged at 298 K. The relative concentration of Zn2+ to Cu2+ $$\left[ {{{\left[ {Z{n^{2 + }}} \right]} \over {\left[ {C{u^{2 + }}} \right]}}} \right]$$ is
A
antilog (24.08)
B
37.3
C
1037.3
D
9.65 $$\times$$ 104
4
AIEEE 2007
MCQ (Single Correct Answer)
+4
-1
The equivalent conductances of two strong electrolytes at infinite dilution in H2O (where ions move freely through a solution) at 25oC are given below:
$$ \wedge _{C{H_3}COONa}^o$$ = 91.0 S cm2/equiv
$$ \wedge _{HCl}^o$$ = 426.2 S cm2/equiv
What additional information/quantity one needs to calculate $$ \wedge ^o$$ of an aqueous solution of acetic acid?
A
$$ \wedge ^o$$ of chloroacetic acid (C/CH2COOH)
B
$$ \wedge ^o$$ of NaCl
C
$$ \wedge ^o$$ of CH3COOK
D
The limiting equivalent conductance of $${H^ + }( \wedge _{{H^ + }}^o)$$
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