Regular use of which of the following fertilizer increases the acidity of soil?

Which of the following nuclear reactions will generate an isotope?

A radioactive element gets spilled over the floor of a room. Its half-life period is 30 days. If the initial activity is ten times the permissible value, after how many days will it be safe to enter the room?

Consider the reaction, 2A + B $$\to$$ products. When concentration of B alone was doubled, the half-life did not change. When the concentration of A alone was doubled, the rate increased by two times. The unit of rate constant for this reaction is