1
AIEEE 2007
MCQ (Single Correct Answer)
+4
-1
Identify the correct statement regarding a spontaneous process :
A
For a spontaneous process in an isolated system, the change in entropy is positive
B
Endothermic processes are never spontaneous
C
Exothermic processes are always spontaneous
D
Lowering of energy in the reaction process is the only criterion for spontaneity
2
AIEEE 2007
MCQ (Single Correct Answer)
+4
-1
In conversion of lime-stone to lime,
CaCO3(s) $$\to$$ CaO(s) + CO2 (g) the vales of ∆H° and ∆S° are +179.1 kJ mol−1 and 160.2 J/K respectively at 298 K and 1 bar. Assuming that ∆H° do not change with temperature, temperature above which conversion of limestone to lime will be spontaneous is :
A
1008 K
B
1200
C
845 K
D
1118 K
3
AIEEE 2007
MCQ (Single Correct Answer)
+4
-1
Which of the following reactions will yield 2, 2-dibromopropane?
A
CH3 - CH = CH2 + HBr $$\to$$
B
CH3 - C $$\equiv$$ CH + 2HBr $$\to$$
C
CH3CH = CHBr + HBr $$\to$$
D
CH $$\equiv$$ CH + 2HBr $$\to$$
4
AIEEE 2007
MCQ (Single Correct Answer)
+4
-1
The actinoids exhibits more number of oxidation states in general than the lanthanoids. This is because :
A
the 5f orbitals are more buried than the 4f orbitals
B
there is a similarity between 4f and 5f orbitals in their angular part of the wave function
C
the actinoids are more reactive than the lanthanoids
D
the 5f orbitals extend further from the nucleus than the 4f orbitals
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