Consider the following E^o values

$$E_{F{e^{3 + }}/F{e^{2 + }}}^o$$ = 0.77 V;

$$E_{S{n^{2 + }}/S{n}}^o$$ = -0.14 V

Under standard conditions the potential for the reaction

Sn(s) + 2Fe³⁺(aq) $$\to$$ 2Fe²⁺(aq) + Sn²⁺(aq) is :

The standard e.m.f of a cell, involving one electron change is found to be 0.591 V at 25^oC. The equilibrium constant of the reaction is (F = 96,500 C mol^-1: R = 8.314 JK^-1 mol^-1)

The limiting molar conductivities Λ° for NaCl, KBr and KCl are 126, 152 and 150 S cm² mol^-1 respectively. The Λ° for NaBr is

In a cell that utilises the reaction Zn(s) + 2H⁺ (aq) $$\to$$ Zn2+(aq) + H2(g) addition of H₂SO₄ to cathode compartment, will