1
JEE Main 2025 (Online) 4th April Morning Shift
MCQ (Single Correct Answer)
+4
-1
Change Language

Given below are two statements:

Statement I: Nitrogen forms oxides with +1 to +5 oxidation states due to the formation of $\mathrm{p} \pi-\mathrm{p} \pi$ bond with oxygen.

Statement II: Nitrogen does not form halides with +5 oxidation state due to the absence of d-orbital in it.

In the light of given statements, choose the correct answer from the options given below.

A
Both Statement I and Statement II are true
B
Statement I is true but Statement II is false
C
Statement I is false but Statement II are true
D
Both Statement I and Statement II are False
2
JEE Main 2025 (Online) 4th April Morning Shift
MCQ (Single Correct Answer)
+4
-1
Change Language

Number of stereoisomers possible for the complexes, $\left[\mathrm{CrCl}_3(\mathrm{py})_3\right]$ and $\left[\mathrm{CrCl}_2(\mathrm{ox})_2\right]^{3-}$ are respectively $(p y=$ pyridine,$o x=$ oxalate $)$

A
3 & 3
B
2 & 3
C
1 & 2
D
2 & 2
3
JEE Main 2025 (Online) 4th April Morning Shift
MCQ (Single Correct Answer)
+4
-1
Change Language

An organic compound $(\mathrm{X})$ with molecular formula $\mathrm{C}_3 \mathrm{H}_6 \mathrm{O}$ is not readily oxidised. On reduction it gives $\mathrm{C}_3 \mathrm{H}_8 \mathrm{O}(\mathrm{Y})$ which reacts with HBr to give a bromide $(\mathrm{Z})$ which is converted to Grignard reagent. This Grignard reagent on reaction with $(\mathrm{X})$ followed by hydrolysis give 2,3-dimethylbutan-2-ol. Compounds $(\mathrm{X}),(\mathrm{Y})$ and $(\mathrm{Z})$ respectively are:

A
$\mathrm{CH}_3 \mathrm{CH}_2 \mathrm{CHO}, \mathrm{CH}_3 \mathrm{CH}_2 \mathrm{CH}_2 \mathrm{OH}, \mathrm{CH}_3 \mathrm{CH}_2 \mathrm{CH}_2 \mathrm{Br}$
B
$\mathrm{CH}_3 \mathrm{COCH}_3, \mathrm{CH}_3 \mathrm{CH}(\mathrm{OH}) \mathrm{CH}_3, \mathrm{CH}_3 \mathrm{CH}(\mathrm{Br}) \mathrm{CH}_3$
C
$\mathrm{CH}_3 \mathrm{COCH}_3, \mathrm{CH}_3 \mathrm{CH}_2 \mathrm{CH}_2 \mathrm{OH}, \mathrm{CH}_3 \mathrm{CH}(\mathrm{Br}) \mathrm{CH}_3$
D
$\mathrm{CH}_3 \mathrm{CH}_2 \mathrm{CHO}, \mathrm{CH}_3 \mathrm{CH}=\mathrm{CH}_2, \mathrm{CH}_3 \mathrm{CH}(\mathrm{Br}) \mathrm{CH}_3$
4
JEE Main 2025 (Online) 4th April Morning Shift
MCQ (Single Correct Answer)
+4
-1
Change Language

Let us consider a reversible reaction at temperature, T. In this reaction, both $\Delta \mathrm{H}$ and $\Delta \mathrm{S}$ were observed to have positive values. If the equilibrium temperature is Te , then the reaction becomes spontaneous at:

A
$\mathrm{Te}>\mathrm{T}$
B
$\mathrm{T}>\mathrm{Te}$
C
$\mathrm{T}=\mathrm{Te}$
D
$\mathrm{Te}=5 \mathrm{~T}$
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