LIST I (Elements) |
LIST II (Properties in their respective groups) |
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---|---|---|---|
A. | $$\mathrm{Cl,S}$$ | I. | Elements with highest electronegativity |
B. | $$\mathrm{Ge,As}$$ | II. | Elements with largest atomic size |
C. | $$\mathrm{Fr,Ra}$$ | III. | Elements which show properties of both metals and non-metal |
D. | $$\mathrm{F,O}$$ | IV. | Elements with highest negative electron gain enthalpy |
Choose the correct answer from the options given below:
Match List I with List II
LIST I (Name of the test) |
LIST II (Reaction sequence involved) [M is metal] |
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A. | Borax bead test | I. | $$\mathrm{MCO}_3 \rightarrow \mathrm{MO} \xrightarrow[+\Delta]{\mathrm{Co}\left(\mathrm{NO}_3\right)_2} \mathrm{CoO} \cdot \mathrm{MO}$$ |
B. | Charcoal cavity test | II. | $$\mathrm{MCO}_3 \rightarrow \mathrm{MCl}_2 \rightarrow \mathrm{M}^{2+}$$ |
C. | Cobalt nitrate test | III. | $$\mathrm{MSO}_4 \xrightarrow[\Delta]{\mathrm{Na}_2 \mathrm{~B}_4 \mathrm{O}_7} \mathrm{M}\left(\mathrm{BO}_2\right)_2 \rightarrow \mathrm{MBO}_2 \rightarrow \mathrm{M}$$ |
D. | Flame test | IV. | $$\mathrm{MSO}_4 \xrightarrow[\Delta]{\mathrm{Na}_2 \mathrm{CO}_3} \mathrm{MCO}_3 \rightarrow \mathrm{MO} \rightarrow \mathrm{M}$$ |
Choose the correct answer from the options given below:
Number of Complexes with even number of electrons in $$\mathrm{t_{2 g}}$$ orbitals is -
$$\left[\mathrm{Fe}\left(\mathrm{H}_2 \mathrm{O}\right)_6\right]^{2+},\left[\mathrm{Co}\left(\mathrm{H}_2 \mathrm{O}\right)_6\right]^{2+},\left[\mathrm{Co}\left(\mathrm{H}_2 \mathrm{O}\right)_6\right]^{3+},\left[\mathrm{Cu}\left(\mathrm{H}_2 \mathrm{O}\right)_6\right]^{2+},\left[\mathrm{Cr}\left(\mathrm{H}_2 \mathrm{O}\right)_6\right]^{2+}$$
For the given hypothetical reactions, the equilibrium constants are as follows :
$$\begin{aligned} & \mathrm{X} \rightleftharpoons \mathrm{Y} ; \mathrm{K}_1=1.0 \\ & \mathrm{Y} \rightleftharpoons \mathrm{Z} ; \mathrm{K}_2=2.0 \\ & \mathrm{Z} \rightleftharpoons \mathrm{W} ; \mathrm{K}_3=4.0 \end{aligned}$$
The equilibrium constant for the reaction $$\mathrm{X} \rightleftharpoons \mathrm{W}$$ is