In the Claisen-Schmidt reaction to prepare $$351 \mathrm{~g}$$ of dibenzalacetone using $$87 \mathrm{~g}$$ of acetone, the amount of benzaldehyde required is _________ g. (Nearest integer)

Combustion of 1 mole of benzene is expressed at

$$\mathrm{C}_6 \mathrm{H}_6(\mathrm{l})+\frac{15}{2} \mathrm{O}_2(\mathrm{~g}) \rightarrow 6 \mathrm{CO}_2(\mathrm{~g})+3 \mathrm{H}_2 \mathrm{O}(\mathrm{l}) \text {. }$$

The standard enthalpy of combustion of $$2 \mathrm{~mol}$$ of benzene is $$-^{\prime} x^{\prime} \mathrm{kJ}$$. $$x=$$ __________.

Given :

1. standard Enthalpy of formation of $$1 \mathrm{~mol}$$ of $$\mathrm{C}_6 \mathrm{H}_6(\mathrm{l})$$, for the reaction $$6 \mathrm{C}$$ (graphite) $$+3 \mathrm{H}_2(\mathrm{g}) \rightarrow \mathrm{C}_6 \mathrm{H}_6(\mathrm{l})$$ is $$48.5 \mathrm{~kJ} \mathrm{~mol}^{-1}$$.

2. Standard Enthalpy of formation of $$1 \mathrm{~mol}$$ of $$\mathrm{CO}_2(\mathrm{g})$$, for the reaction $$\mathrm{C}$$ (graphite) $$+\mathrm{O}_2(\mathrm{g}) \rightarrow \mathrm{CO}_2(\mathrm{g})$$ is $$-393.5 \mathrm{~kJ} \mathrm{~mol}^{-1}$$.

3. Standard and Enthalpy of formation of $$1 \mathrm{~mol}$$ of $$\mathrm{H}_2 \mathrm{O}(\mathrm{l})$$, for the reaction $$\mathrm{H}_2(\mathrm{g})+\frac{1}{2} \mathrm{O}_2(\mathrm{g}) \rightarrow \mathrm{H}_2 \mathrm{O}(\mathrm{l})$$ is $$-286 \mathrm{~kJ} \mathrm{~mol}^{-1}$$.

$$\mathrm{X} \mathrm{~g}$$ of ethanamine was subjected to reaction with $$\mathrm{NaNO}_2 / \mathrm{HCl}$$ followed by hydrolysis to liberate $$\mathrm{N}_2$$ and $$\mathrm{HCl}$$. The $$\mathrm{HCl}$$ generated was completely neutralised by 0.2 moles of $$\mathrm{NaOH} . \mathrm{X}$$ is _________ g.

Number of compounds from the following with zero dipole moment is _________.

$$\mathrm{HF}, \mathrm{H}_2, \mathrm{H}_2 \mathrm{~S}, \mathrm{CO}_2, \mathrm{NH}_3, \mathrm{BF}_3, \mathrm{CH}_4, \mathrm{CHCl}_3, \mathrm{SiF}_4, \mathrm{H}_2 \mathrm{O}, \mathrm{BeF}_2$$