The enthalpy of combustion of propane, graphite and dihydrogen at $$298 \mathrm{~K}$$ are $$-2220.0 \mathrm{~kJ} \mathrm{~mol}^{-1},-393.5 \mathrm{~kJ} \mathrm{~mol}^{-1}$$ and $$-285.8 \mathrm{~kJ} \mathrm{~mol}^{-1}$$ respectively. The magnitude of enthalpy of formation of propane $$\left(\mathrm{C}_{3} \mathrm{H}_{8}\right)$$ is _______________ $$\mathrm{kJ} \,\mathrm{mol}^{-1}$$. (Nearest integer)

The cell potential for $$\mathrm{Zn}\left|\mathrm{Zn}^{2+}(\mathrm{aq})\right|\left|\mathrm{Sn}^{x+}\right| \mathrm{Sn}$$ is $$0.801 \mathrm{~V}$$ at $$298 \mathrm{~K}$$. The reaction quotient for the above reaction is $$10^{-2}$$. The number of electrons involved in the given electrochemical cell reaction is ____________.

$$\left(\right.$$ Given $$: \mathrm{E}_{\mathrm{Zn}^{2+} \mid \mathrm{Zn}}^{\mathrm{o}}=-0.763 \mathrm{~V}, \mathrm{E}_{\mathrm{Sn}^{x+} \mid \mathrm{Sn}}^{\mathrm{o}}=+0.008 \mathrm{~V}$$ and $$\left.\frac{2.303 \mathrm{RT}}{\mathrm{F}}=0.06 \mathrm{~V}\right)$$

The half life for the decomposition of gaseous compound $$\mathrm{A}$$ is $$240 \mathrm{~s}$$ when the gaseous pressure was 500 Torr initially. When the pressure was 250 Torr, the half life was found to be $$4.0$$ min. The order of the reaction is ______________. (Nearest integer)

Consider the following metal complexes :

$$\left[\mathrm{Co}\left(\mathrm{NH}_{3}\right)_{6}\right]^{3+}$$

$$\left[\mathrm{CoCl}\left(\mathrm{NH}_{3}\right)_{5}\right]^{2+}$$

$$\left[\mathrm{Co}(\mathrm{CN})_{6}\right]^{3-}$$

$$\left[\mathrm{Co}\left(\mathrm{NH}_{3}\right)_{5}\left(\mathrm{H}_{2} \mathrm{O}\right)\right]^{3+}$$

The spin-only magnetic moment value of the complex that absorbes light with shortest wavelength is _____________ B. M. (Nearest integer)