The magnitude of the change in oxidising power of the $$MnO_4^ - /M{n^{2 + }}$$ couple is x $$\times$$ 10^$$-$$4 V, if the H⁺ concentration is decreased from 1M to 10^$$-$$4 M at 25$$^\circ$$C. (Assume concentration of $$MnO_4^ - $$ and $$M{n^{2 + }}$$ to be same on change in H⁺ concentration). The value of x is ___________. $$\left[ {Given\,:{{2.303RT} \over F} = 0.059} \right]$$

Potassium chlorate is prepared by the electrolysis of KCl in basic solution

6OH^- + Cl^- $$ \to $$ ClO₃^- + 3H₂O + 6e^-

If only 60% of the current is utilized in the reaction, the time (rounded to the nearest hour) required to produce 10 g of KClO₃ using a current of 2 A is_________.

(Given : F = 96,500 C mol^–1; molar mass of KCIO₃ = 122 g mol^–1)

An oxidation-reduction reaction in which
3 electrons are transferred has a $$\Delta $$Gº of 17.37 kJ mol^–1 at
25 ^oC. The value of E^o
cell (in V) is ______ × 10^–2.
(1 F = 96,500 C mol^–1)

An acidic solution of dichromate is electrolyzed for 8 minutes using 2A current. As per the following equation
Cr₂O₇^2- + 14H⁺ + 6e^– $$ \to $$ 2Cr³⁺ + 7H₂O
The amount of Cr³⁺ obtained was 0.104 g. The efficiency of the process(in%) is (Take : F = 96000 C, At. mass of chromium = 52) ______.