Consider the following electrochemical cell at standard condition.

$$\mathrm{Au}(\mathrm{~s})\left|\mathrm{QH}_2, \mathrm{Q}\right| \mathrm{NH}_4 \mathrm{X}(0.01 \mathrm{M})| | \mathrm{Ag}^{+}(1 \mathrm{M}) \mid \mathrm{Ag}(\mathrm{~s}) \mathrm{E}_{\text {cell }}=+0.4 \mathrm{~V}$$

The couple $\mathrm{QH}_2 / \mathrm{Q}$ represents quinhydrone electrode, the half cell reaction is given below:

$$\left[\text { Given : } \mathrm{E}_{\mathrm{Ag}^{+} / \mathrm{Ag}}^0=+0.8 \mathrm{~V} \text { and } \frac{2.303 \mathrm{RT}}{\mathrm{~F}}=0.06 \mathrm{~V}\right]$$

The $\mathrm{pK}_{\mathrm{b}}$ value of the ammonium halide salt $\left(\mathrm{NH}_4 \mathrm{X}\right)$ used here is __________ . (nearest integer)

Electrolysis of 600 mL aqueous solution of NaCl for 5 min changes the pH of the solution to 12 .

The current in Amperes used for the given electrolysis is ___________ . (Nearest integer).

Given below is the plot of the molar conductivity vs $\sqrt{\text { concentration }}$ for KCl in aqueous solution.

If, for the higher concentration of KCl solution, the resistance of the conductivity cell is $100 \Omega$, then the resistance of the same cell with the dilute solution is ' x ' $\Omega$

The value of $x$ is _________ (Nearest integer)

The standard reduction potentials at $$298 \mathrm{~K}$$ for the following half cells are given below :

$$\mathrm{Cr}_2 \mathrm{O}_7^{2-}+14 \mathrm{H}^{+}+6 \mathrm{e}^{-} \rightarrow 2 \mathrm{Cr}^{3+}+7 \mathrm{H}_2 \mathrm{O}, \quad \mathrm{E}^{\circ}=1.33 \mathrm{~V}$$

$$\begin{array}{ll} \mathrm{Fe}^{3+}(\mathrm{aq})+3 \mathrm{e}^{-} \rightarrow \mathrm{Fe} & \mathrm{E}^{\circ}=-0.04 \mathrm{~V} \\ \mathrm{Ni}^{2+}(\mathrm{aq})+2 \mathrm{e}^{-} \rightarrow \mathrm{Ni} & \mathrm{E}^{\circ}=-0.25 \mathrm{~V} \\ \mathrm{Ag}^{+}(\mathrm{aq})+\mathrm{e}^{-} \rightarrow \mathrm{Ag} & \mathrm{E}^{\circ}=0.80 \mathrm{~V} \\ \mathrm{Au}^{3+}(\mathrm{aq})+3 \mathrm{e}^{-} \rightarrow \mathrm{Au} & \mathrm{E}^{\circ}=1.40 \mathrm{~V} \end{array}$$

Consider the given electrochemical reactions,

The number of metal(s) which will be oxidized be $$\mathrm{Cr}_2 \mathrm{O}_7^{2-}$$, in aqueous solution is _________.