In an electrochemical reaction of lead, at standard temperature, if $$\mathrm{E}^{0}\left(\mathrm{~Pb}^{2+} / \mathrm{Pb}\right)=\mathrm{m}$$ Volt and $$\mathrm{E}^{0}\left(\mathrm{~Pb}^{4+} / \mathrm{Pb}\right)=\mathrm{n}$$ Volt, then the value of $$\mathrm{E}^{0}\left(\mathrm{~Pb}^{2+} / \mathrm{Pb}^{4+}\right)$$ is given by $$\mathrm{m-x n}$$. The value of $$\mathrm{x}$$ is ___________. (Nearest integer)

The specific conductance of $$0.0025 ~\mathrm{M}$$ acetic acid is $$5 \times 10^{-5} \mathrm{~S} \mathrm{~cm}^{-1}$$ at a certain temperature. The dissociation constant of acetic acid is __________ $$\times ~10^{-7}$$ (Nearest integer)

Consider limiting molar conductivity of $$\mathrm{CH}_{3} \mathrm{COOH}$$ as $$400 \mathrm{~S} \mathrm{~cm}^{2} \mathrm{~mol}^{-1}$$

$$\mathrm{FeO_4^{2 - }\buildrel { + 2.2V} \over \longrightarrow F{e^{3 + }}\buildrel { + 0.70V} \over \longrightarrow F{e^{2 + }}\buildrel { - 0.45V} \over \longrightarrow F{e^0}}$$

$$E_{FeO_4^{2 - }/F{e^{2 + }}}^\theta $$ is $$x \times {10^{ - 3}}$$ V. The value of $$x$$ is _________

The number of incorrect statements from the following is ___________.

A. The electrical work that a reaction can perform at constant pressure and temperature is equal to the reaction Gibbs energy.

B. $$\mathrm{E_{cell}^{\circ}}$$ cell is dependent on the pressure.

C. $$\frac{d E^{\theta} \text { cell }}{\mathrm{dT}}=\frac{\Delta_{\mathrm{r}} \mathrm{S}^{\theta}}{\mathrm{nF}}$$

D. A cell is operating reversibly if the cell potential is exactly balanced by an opposing source of potential difference.