1
JEE Main 2021 (Online) 1st September Evening Shift
Numerical
+4
-1
If the conductivity of mercury at 0$$^\circ$$C is 1.07 $$\times$$ 106 S m$$-$$1 and the resistance of a cell containing mercury is 0.243$$\Omega$$, then the cell constant of the cell is x $$\times$$ 104 m$$-$$1. The value of x is ____________. (Nearest integer)
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2
JEE Main 2021 (Online) 31st August Morning Shift
Numerical
+4
-1
Consider the following cell reaction :
$$C{d_{(s)}} + H{g_2}S{O_{4(s)}} + {9 \over 5}{H_2}{O_{(l)}}$$ $$\rightleftharpoons$$ $$CdS{O_4}.{9 \over 5}{H_2}{O_{(s)}} + 2H{g_{(l)}}$$
The value of $$E_{cell}^0$$ is 4.315 V at 25$$^\circ$$C. If $$\Delta$$H$$^\circ$$ = $$-$$825.2 kJ mol$$-$$1, the standard entropy change $$\Delta$$S$$^\circ$$ in J K$$-$$1 is ___________. (Nearest integer) [Given : Faraday constant = 96487 C mol$$-$$1]
$$C{d_{(s)}} + H{g_2}S{O_{4(s)}} + {9 \over 5}{H_2}{O_{(l)}}$$ $$\rightleftharpoons$$ $$CdS{O_4}.{9 \over 5}{H_2}{O_{(s)}} + 2H{g_{(l)}}$$
The value of $$E_{cell}^0$$ is 4.315 V at 25$$^\circ$$C. If $$\Delta$$H$$^\circ$$ = $$-$$825.2 kJ mol$$-$$1, the standard entropy change $$\Delta$$S$$^\circ$$ in J K$$-$$1 is ___________. (Nearest integer) [Given : Faraday constant = 96487 C mol$$-$$1]
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3
JEE Main 2021 (Online) 27th August Evening Shift
Numerical
+4
-1
The resistance of a conductivity cell with cell constant 1.14 cm$$-$$1, containing 0.001 M KCl at 298 K is 1500 $$\Omega$$. The molar conductivity of 0.001 M KCl solution at 298 K in S cm2 mol$$-$$1 is ____________. (Integer answer)
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4
JEE Main 2021 (Online) 26th August Evening Shift
Numerical
+4
-1
For the galvanic cell,
Zn(s) + Cu2+ (0.02 M) $$\to$$ Zn2+ (0.04 M) + Cu(s),
Ecell = ______________ $$\times$$ 10$$-$$2 V. (Nearest integer)
[Use : $$E_{Cu/C{u^{2 + }}}^0$$ = $$-$$ 0.34 V, $$E_{Zn/Z{n^{2 + }}}^0$$ = + 0.76 V, $${{2.303RT} \over F} = 0.059\,V$$]
Zn(s) + Cu2+ (0.02 M) $$\to$$ Zn2+ (0.04 M) + Cu(s),
Ecell = ______________ $$\times$$ 10$$-$$2 V. (Nearest integer)
[Use : $$E_{Cu/C{u^{2 + }}}^0$$ = $$-$$ 0.34 V, $$E_{Zn/Z{n^{2 + }}}^0$$ = + 0.76 V, $${{2.303RT} \over F} = 0.059\,V$$]
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