1
JEE Main 2022 (Online) 25th July Morning Shift
Numerical
+4
-1
Change Language

The cell potential for $$\mathrm{Zn}\left|\mathrm{Zn}^{2+}(\mathrm{aq})\right|\left|\mathrm{Sn}^{x+}\right| \mathrm{Sn}$$ is $$0.801 \mathrm{~V}$$ at $$298 \mathrm{~K}$$. The reaction quotient for the above reaction is $$10^{-2}$$. The number of electrons involved in the given electrochemical cell reaction is ____________.

$$\left(\right.$$ Given $$: \mathrm{E}_{\mathrm{Zn}^{2+} \mid \mathrm{Zn}}^{\mathrm{o}}=-0.763 \mathrm{~V}, \mathrm{E}_{\mathrm{Sn}^{x+} \mid \mathrm{Sn}}^{\mathrm{o}}=+0.008 \mathrm{~V}$$ and $$\left.\frac{2.303 \mathrm{RT}}{\mathrm{F}}=0.06 \mathrm{~V}\right)$$

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2
JEE Main 2022 (Online) 29th June Evening Shift
Numerical
+4
-1
Change Language

The cell potential for the given cell at 298 K

Pt| H2 (g, 1 bar) | H+ (aq) || Cu2+ (aq) | Cu(s)

is 0.31 V. The pH of the acidic solution is found to be 3, whereas the concentration of Cu2+ is 10$$-$$x M. The value of x is ___________.

(Given : $$E_{C{u^{2 + }}/Cu}^\Theta $$ = 0.34 V and $${{2.303\,RT} \over F}$$ = 0.06 V)

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3
JEE Main 2022 (Online) 29th June Morning Shift
Numerical
+4
-1
Change Language

A dilute solution of sulphuric acid is electrolysed using a current of 0.10 A for 2 hours to produce hydrogen and oxygen gas. The total volume of gases produced a STP is _____________ cm3. (Nearest integer)

[Given : Faraday constant F = 96500 C mol$$-$$1 at STP, molar volume of an ideal gas is 22.7 L mol$$-$$1]

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4
JEE Main 2022 (Online) 28th June Evening Shift
Numerical
+4
-1
Change Language

For the given reactions

Sn2+ + 2e$$-$$ $$\to$$ Sn

Sn4+ + 4e$$-$$ $$\to$$ Sn

the electrode potentials are ; $$E_{S{n^{2 + }}/Sn}^o = - 0.140$$ V and $$E_{S{n^{4 + }}/Sn}^o = + 0.010$$ V. The magnitude of standard electrode potential for $$S{n^{4 + }}/S{n^{2 + }}$$ i.e. $$E_{S{n^{4 + }}/S{n^{2 + }}}^o$$ is _____________ $$\times$$ 10$$-$$2 V. (Nearest integer)

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