Match List - I with List - II.

Choose the correct answer from the options given below :

Given below are two statements:

Statement (I) : Molal depression constant $\mathrm{K}_f$ is given by $\frac{\mathrm{M}_1 \mathrm{RT}_f}{\Delta \mathrm{~S}_{\mathrm{fus}}}$, where symbols have their usual meaning.

Statement (II) : $\mathrm{K}_f$ for benzene is less than the $\mathrm{K}_f$ for water.

In the light of the above statements, choose the most appropriate answer from the options given below :

$X Y$ is the membrane/partition between two chambers 1 and 2 containing sugar solutions of concentration $c_1$ and $c_2\left(c_1>c_2\right) \mathrm{mol} \mathrm{L}^{-1}$. For the reverse osmosis to take place identify the correct condition.

(Here $p_1$ and $p_2$ are pressures applied on chamber 1 and 2 ).

A. Membrane/Partition : Cellophane, $\mathrm{p}_1>\pi$

B. Membrane/Partition : Porous, $\mathrm{p}_2>\pi$

C. Membrane/Partition : Parchment paper, $p_1>\pi$

D. Membrane/Partition : Cellophane, $\mathrm{p}_2>\pi$

Choose the correct answer from the option given below:

10 mL of 2 M NaOH solution is added to 20 mL of 1 M HCl solution kept in a beaker. Now, 10 mL of this mixture is poured into a volumetric flask of 100 mL containing 2 moles of HCl and made the volume upto the mark with distilled water. The solution in this flask is :