Given below are two statements :

Statement I : $\quad \mathrm{H}_2 \mathrm{O}$ molecules move from the chamber 1 to chamber 2 .

Statement II : The osmotic pressure of a solution prepared by dissolving 50 mg of potassium sulphate (molar mass $=174 \mathrm{~g} / \mathrm{mol}$ ) in 2 L of water (at $27^{\circ} \mathrm{C}$ ) is 0.0107 bar. (Given: $\mathrm{R}=0.083 \mathrm{dm}^3$ bar $\mathrm{K}^{-1} \mathrm{~mol}^{-1}$ and assume complete dissociation of electrolyte)

In the light of the above statements, choose the correct answer from the options given below :

When 0.25 moles of a non-volatile, non-ionizable solute was dissolved in 1 mole of a solvent the vapor pressure of solution was $x \%$ of vapor pressure of pure solvent. What is $x \%$ ?

At $27^{\circ} \mathrm{C}, 0.1 \mathrm{M}, 1 \mathrm{~L} \mathrm{~K}_4\left[\mathrm{Fe}(\mathrm{CN})_6\right]$ aqueous solution and $0.1 \mathrm{M}, 1 \mathrm{~L} \mathrm{FeCl}_3$ aqueous solution are placed in a container separated by a semi permeable membrane AB . Assume complete dissociation of both the solutes. Which of the following statement is correct?

Solution A is prepared by dissolving 1 g of a protein (molar mass = 50,000 g mol^-1) in 0.5 L of water at 300 K. Its osmotic pressure is $x$ bar. Solution B is made by dissolving 2 g of the same protein in 1 L of water at 300 K. Osmotic pressure of solution B is $y$ bar. Entire solution of A is mixed with entire solution of B at the same temperature. The osmotic pressure of resultant solution is $z$ bar. $x$, $y$ and $z$ respectively are:
(R = 0.083 L bar mol^-1 K^-1)