Molal depression constant for a solvent is 4.0 kg mol^–1. The depression in the freezing point of the solvent for 0.03 mol kg^–1 solution of K₂SO₄ is :
(Assume complete dissociation of the electrolyte)

The osmotic pressure of a dilute solution of an ionic compound XY in water is four times that of a solution of 0.01 M BaCl₂ in water. Assuming complete dissociation of the given ionic compounds in water, the concentration of XY (in mol L^–1) in solution is :

Liquid 'M' and liquid 'N' form an ideal solution. The vapour pressures of pure liquids 'M' and 'N' are 450 and 700 mmHg, respectively, at the same temperature. Then correct statement is:
(x_M = Mole fraction of 'M' in solution ;
x_N = Mole fraction of 'N' in solution ;
y_M = Mole fraction of 'M' in vapour phase ;
y_N = Mole fraction of 'N' in vapour phase)

For the solution of the gases w, x, y and z in water at 298K, the Henrys law constants (K_H) are 0.5, 2, 35 and 40 kbar, respectively. The correct plot for the given data is :-