What weight of glucose must be dissolved in $$100 \mathrm{~g}$$ of water to lower the vapour pressure by $$0.20 \mathrm{~mm} ~\mathrm{Hg}$$ ?

(Assume dilute solution is being formed)

Given : Vapour pressure of pure water is $$54.2 \mathrm{~mm} ~\mathrm{Hg}$$ at room temperature. Molar mass of glucose is $$180 \mathrm{~g} \mathrm{~mol}^{-1}$$

Evaluate the following statements for their correctness.

A. The elevation in boiling point temperature of water will be same for $0.1 \mathrm{M} \, \mathrm{NaCl}$ and $0.1 \mathrm{M}$ urea.

B. Azeotropic mixtures boil without change in their composition.

C. Osmosis always takes place from hypertonic to hypotonic solution.

D. The density of $32 \% \, \mathrm{H}_{2} \mathrm{SO}_{4}$ solution having molarity $4.09 ~\mathrm{M}$ is approximately $1.26 \mathrm{~g} \mathrm{~mL}^{-1}$

E. A negatively charged sol is obtained when KI solution is added to silver nitrate solution.

Choose the correct answer from the options given below :

Match List I with List II

	List I		List II
A.	van't Hoff factor, i	I.	Cryoscopic constant
B.	$$\mathrm{k_f}$$	II.	Isotonic solutions
C.	Solutions with same osmotic pressure	III.	$$\mathrm{\frac{Normal\,molar\,mass}{Abnormal\,molar\,mass}}$$
D.	Azeotropes	IV.	Solutions with same composition of vapour above it

Choose the correct answer from the options given below :