Liquid A and B form an ideal solution. The vapour pressures of pure liquids A and B are 350 and 750 mm Hg respectively at the same temperature. If $x_A$ and $x_B$ are the mole fraction of A and B in solution while $y_A$ and $y_B$ are the mole fraction of A and B in vapour phase, then,
Match List - I with List - II.
List - I | List - II |
---|---|
(A) Solution of chloroform and acetone | (I) Minimum boiling azeotrope |
(B) Solution of ethanol and water | (II) Dimerizes |
(C) Solution of benzene and toluene | (III) Maximum boiling azeotrope |
(D) Solution of acetic acid in benzene | (IV) ΔVmix = 0 |
Choose the correct answer from the options given below :
Given below are two statements:
Statement (I) : Molal depression constant $\mathrm{K}_f$ is given by $\frac{\mathrm{M}_1 \mathrm{RT}_f}{\Delta \mathrm{~S}_{\mathrm{fus}}}$, where symbols have their usual meaning.
Statement (II) : $\mathrm{K}_f$ for benzene is less than the $\mathrm{K}_f$ for water.
In the light of the above statements, choose the most appropriate answer from the options given below :
$X Y$ is the membrane/partition between two chambers 1 and 2 containing sugar solutions of concentration $c_1$ and $c_2\left(c_1>c_2\right) \mathrm{mol} \mathrm{L}^{-1}$. For the reverse osmosis to take place identify the correct condition.
(Here $p_1$ and $p_2$ are pressures applied on chamber 1 and 2 ).
A. Membrane/Partition : Cellophane, $\mathrm{p}_1>\pi$
B. Membrane/Partition : Porous, $\mathrm{p}_2>\pi$
C. Membrane/Partition : Parchment paper, $p_1>\pi$
D. Membrane/Partition : Cellophane, $\mathrm{p}_2>\pi$
Choose the correct answer from the option given below: