Arrange the following solutions in order of their increasing boiling points.

(i) $10^{-4} \mathrm{M} \mathrm{NaCl}$

(ii) $10^{-4} \mathrm{M}$ Urea

(iii) $10^{-3} \mathrm{M} \mathrm{NaCl}$

(iv) $10^{-2} \mathrm{M} \mathrm{NaCl}$

$$0.05 \mathrm{M} \mathrm{~CuSO}_4$$ when treated with $$0.01 \mathrm{M} \mathrm{~K}_2 \mathrm{Cr}_2 \mathrm{O}_7$$ gives green colour solution of $$\mathrm{Cu}_2 \mathrm{Cr}_2 \mathrm{O}_7$$. The two solutions are separated as shown below : [SPM : Semi Permeable Membrane]

Due to osmosis :

Identify the mixture that shows positive deviations from Raoult's Law