In an adiabatic process, which of the following statements is true?

The equation for real gas is given by $\left(\mathrm{P}+\frac{\mathrm{a}}{\mathrm{V}^2}\right)(\mathrm{V}-\mathrm{b})=\mathrm{RT}$, where $\mathrm{P}, \mathrm{V}, \mathrm{T}$ and R are the pressure, volume, temperature and gas constant, respectively. The dimension of $\mathrm{ab}^{-2}$ is equivalent to that of :

The difference of temperature in a material can convert heat energy into electrical energy. To harvest the heat energy, the material should have

Given below are two statements. One is labelled as Assertion (A) and the other is labelled as Reason (R).

Assertion (A) : With the increase in the pressure of an ideal gas, the volume falls off more rapidly in an isothermal process in comparison to the adiabatic process.

Reason (R) : In isothermal process, PV = constant, while in adiabatic process $PV^{\gamma}$ = constant. Here $\gamma$ is the ratio of specific heats, P is the pressure and V is the volume of the ideal gas.

In the light of the above statements, choose the correct answer from the options given below: