For a diatomic gas, if $\gamma_1=\left(\frac{C p}{C v}\right)$ for rigid molecules and $\gamma_2=\left(\frac{C p}{C v}\right)$ for another diatomic molecules, but also having vibrational modes. Then, which one of the following options is correct? (Cp and Cv are specific heats of the gas at constant pressure and volume)

Two spherical bodies of same materials having radii 0.2 m and 0.8 m are placed in same atmosphere. The temperature of the smaller body is 800 K and temperature of the bigger body is 400 K . If the energy radiated from the smaller body is E, the energy radiated from the bigger body is (assume, effect of the surrounding temperature to be negligible),

An amount of ice of mass $10^{-3} \mathrm{~kg}$ and temperature $-10^{\circ} \mathrm{C}$ is transformed to vapour of temperature $110^{\circ} \mathrm{C}$ by applying heat. The total amount of work required for this conversion is, (Take, specific heat of ice $=2100 \mathrm{Jkg}^{-1} \mathrm{~K}^{-1}$, specific heat of water $=4180 \mathrm{Jkg}^{-1} \mathrm{~K}^{-1}$, specific heat of steam $=1920 \mathrm{Jkg}^{-1} \mathrm{~K}^{-1}$, Latent heat of ice $=3.35 \times 10^5 \mathrm{Jkg}^{-1}$ and Latent heat of steam $=2.25 \times 10^6$ $\mathrm{Jkg}^{-1}$ )

A real gas within a closed chamber at $$27^{\circ} \mathrm{C}$$ undergoes the cyclic process as shown in figure. The gas obeys $$P V^3=R T$$ equation for the path $$A$$ to $$B$$. The net work done in the complete cycle is (assuming $$R=8 \mathrm{~J} / \mathrm{mol} \mathrm{K}$$):