4.0 moles of argon and 5.0 moles of PCl₅ are introduced into an evacuated flask of 100 litre capacity at 610 K. The system is allowed to equilibrate. At equilibrium, the total pressure of mixture was found to be 6.0 atm. The K_p for the reaction is :

[Given : R = 0.082 L atm K^$$-$$1 mol^$$-$$1]

For a reaction at equilibrium

A(g) $$\rightleftharpoons$$ B(g) + $${1 \over 2}$$ C(g)

the relation between dissociation constant (K), degree of dissociation ($$\alpha$$) and equilibrium pressure (p) is given by :

The value of K_C is 64 at 800 K for the reaction

N₂(g) + 3H₂(g) ⇌ 2NH₃(g)

The value of K_C for the following reaction is :

NH₃(g) ⇌ $${1 \over 2}$$N₂(g) + $${3 \over 2}$$H₂(g)

The variation of equilibrium constant with temperature is given below :

Temperature	Equilibrium Constant
T1 = 25oC	K1 = 10
T2 = 100oC	K2 = 100

The values of $$\Delta $$H^o, $$\Delta $$G^o at
T₁ and $$\Delta $$G^o at T₂ (in kJ mol^–1) respectively, are close to :
[Use R = 8.314 J K^–1 mol^–1]