In an adiabatic process, which of the following statements is true?

The equation for real gas is given by $\left(\mathrm{P}+\frac{\mathrm{a}}{\mathrm{V}^2}\right)(\mathrm{V}-\mathrm{b})=\mathrm{RT}$, where $\mathrm{P}, \mathrm{V}, \mathrm{T}$ and R are the pressure, volume, temperature and gas constant, respectively. The dimension of $\mathrm{ab}^{-2}$ is equivalent to that of :

The difference of temperature in a material can convert heat energy into electrical energy. To harvest the heat energy, the material should have