1
JEE Main 2024 (Online) 6th April Evening Shift
MCQ (Single Correct Answer)
+4
-1

Given below are two statements :

Statement I: $$\mathrm{PF}_5$$ and $$\mathrm{BrF}_5$$ both exhibit $$\mathrm{sp}^3 \mathrm{~d}$$ hybridisation.

Statement II: Both $$\mathrm{SF}_6$$ and $$[\mathrm{Co}(\mathrm{NH}_3)_6]^{3+}$$ exhibit $$\mathrm{sp}^3 \mathrm{~d}^2$$ hybridisation.

In the light of the above statements, choose the correct answer from the options given below :

A
Both Statement I and Statement II are false
B
Statement I is true but Statement II is false
C
Statement I is false but Statement II is true
D
Both Statement I and Statement II are true
2
JEE Main 2024 (Online) 6th April Evening Shift
MCQ (Single Correct Answer)
+4
-1

Match List I with List II.

LIST I
Tetrahedral Complex
LIST II
Electronic configuration
A. $$
\mathrm{TiCl}_4
$$
I. $$
\mathrm{e}^2, \mathrm{t}_2^0
$$
B. $$
\left[\mathrm{FeO}_4\right]^{2-}
$$
II. $$
\mathrm{e^4, t_2^3}
$$
C. $$
\left[\mathrm{FeCl}_4\right]^{-}
$$
III. $$
\mathrm{e}^0, \mathrm{t}_2^0
$$
D. $$
\left[\mathrm{CoCl}_4\right]^{2-}
$$
IV. $$
\mathrm{e}^2, \mathrm{t}_2^3
$$

Choose the correct answer from the options given below :

A
(A)-(IV), (B)-(III), (C)-(I), (D)-(II)
B
(A)-(III), (B)-(I), (C)-(IV), (D)-(II)
C
(A)-(I), (B)-(III), (C)-(IV), (D)-(II)
D
(A)-(III), (B)-(IV), (C)-(II), (D)-(I)
3
JEE Main 2024 (Online) 6th April Evening Shift
MCQ (Single Correct Answer)
+4
-1

Molality $$(\mathrm{m})$$ of $$3 \mathrm{M}$$ aqueous solution of $$\mathrm{NaCl}$$ is : (Given : Density of solution $$=1.25 \mathrm{~g} \mathrm{~mL}^{-1}$$, Molar mass in $$\mathrm{g} \mathrm{~mol}^{-1}: \mathrm{Na}-23, \mathrm{Cl}-35.5$$)

A
2.90 m
B
3.85 m
C
1.90 m
D
2.79 m
4
JEE Main 2024 (Online) 6th April Evening Shift
MCQ (Single Correct Answer)
+4
-1

Evaluate the following statements related to group 14 elements for their correctness.

(A) Covalent radius decreases down the group from $$\mathrm{C}$$ to $$\mathrm{Pb}$$ in a regular manner.

(B) Electronegativity decreases from $$\mathrm{C}$$ to $$\mathrm{Pb}$$ down the group gradually.

(C) Maximum covalance of $$\mathrm{C}$$ is 4 whereas other elements can expand their covalance due to presence of d orbitals.

(D) Heavier elements do not form $$\mathrm{p} \pi-\mathrm{p} \pi$$ bonds.

(E) Carbon can exhibit negative oxidation states.

Choose the correct answer from the options given below :

A
(A), (B) and (C) Only
B
(A) and (B) Only
C
(C), (D) and (E) Only
D
(C) and (D) Only
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