1
JEE Main 2024 (Online) 4th April Morning Shift
MCQ (Single Correct Answer)
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Number of elements from the following that CANNOT form compounds with valencies which match with their respective group valencies is ________. B, C, N, S, O, F, P, Al, Si

A
7
B
3
C
5
D
6
2
JEE Main 2024 (Online) 4th April Morning Shift
Numerical
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$$2.5 \mathrm{~g}$$ of a non-volatile, non-electrolyte is dissolved in $$100 \mathrm{~g}$$ of water at $$25^{\circ} \mathrm{C}$$. The solution showed a boiling point elevation by $$2^{\circ} \mathrm{C}$$. Assuming the solute concentration is negligible with respect to the solvent concentration, the vapor pressure of the resulting aqueous solution is _________ $$\mathrm{mm}$$ of $$\mathrm{Hg}$$ (nearest integer)

[Given : Molal boiling point elevation constant of water $\left(\mathrm{K}_{\mathrm{b}}\right)=0.52 \mathrm{~K} . \mathrm{kg} \mathrm{mol}^{-1}$, $$1 \mathrm{~atm}$$ pressure $$=760 \mathrm{~mm}$$ of $$\mathrm{Hg}$$, molar mass of water $$=18 \mathrm{~g} \mathrm{~mol}^{-1}]$$

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3
JEE Main 2024 (Online) 4th April Morning Shift
Numerical
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Only $$2 \mathrm{~mL}$$ of $$\mathrm{KMnO}_4$$ solution of unknown molarity is required to reach the end point of a titration of $$20 \mathrm{~mL}$$ of oxalic acid $$(2 \mathrm{M})$$ in acidic medium. The molarity of $$\mathrm{KMnO}_4$$ solution should be ________ M.

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4
JEE Main 2024 (Online) 4th April Morning Shift
Numerical
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Consider the following transformation involving first order elementary reaction in each step at constant temperature as shown below.

JEE Main 2024 (Online) 4th April Morning Shift Chemistry - Chemical Kinetics and Nuclear Chemistry Question 34 English

Some details of the above reactions are listed below.

Step Rate constant (sec$$^{-1}$$) Activation energy (kJ mol$$^{-1}$$)
1 $$\mathrm{k_1}$$ 300
2 $$\mathrm{k_2}$$ 200
3 $$\mathrm{k_3}$$ $$\mathrm{Ea_3}$$

If the overall rate constant of the above transformation (k) is given as $$\mathrm{k=\frac{k_1 k_2}{k_3}}$$ and the overall activation energy $$(\mathrm{E}_{\mathrm{a}})$$ is $$400 \mathrm{~kJ} \mathrm{~mol} \mathrm{~m}^{-1}$$, then the value of $$\mathrm{Ea}_3$$ is ________ integer)

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