Number of complexes from the following with even number of unpaired "$$\mathrm{d}$$" electrons is ________ $$[\mathrm{V}(\mathrm{H}_2 \mathrm{O})_6]^{3+},[\mathrm{Cr}(\mathrm{H}_2 \mathrm{O})_6]^{2+},[\mathrm{Fe}(\mathrm{H}_2 \mathrm{O})_6]^{3+},[\mathrm{Ni}(\mathrm{H}_2 \mathrm{O})_6]^{3+},[\mathrm{Cu}(\mathrm{H}_2 \mathrm{O})_6]^{2+}$$ [Given atomic numbers: $$\mathrm{V}=23, \mathrm{Cr}=24, \mathrm{Fe}=26, \mathrm{Ni}=28 \mathrm{Cu}=29$$]
What will be the decreasing order of basic strength of the following conjugate bases? $${ }^{-} \mathrm{OH}, \mathrm{R} \overline{\mathrm{O}}, \mathrm{CH}_3 \mathrm{CO} \overline{\mathrm{O}}, \mathrm{Cl}$$
Given below are two statements :
Statements I : Acidity of $$\alpha$$-hydrogens of aldehydes and ketones is responsible for Aldol reaction.
Statement II : Reaction between benzaldehyde and ethanal will NOT give Cross - Aldol product.
In the light of the above statements, choose the most appropriate answer from the options given below :
Match List I with List II :
LIST I Mechanism steps |
LIST II Effect |
||
---|---|---|---|
A. | I. | $$-$$ E effect | |
B. | II. | $$-$$ R effect | |
C. | III. | $$+$$ E effect | |
D. | IV. | $$+$$ R effect |
Choose the correct answer from the options given below :