1
JEE Main 2024 (Online) 4th April Morning Shift
MCQ (Single Correct Answer)
+4
-1

Number of complexes from the following with even number of unpaired "$$\mathrm{d}$$" electrons is ________ $$[\mathrm{V}(\mathrm{H}_2 \mathrm{O})_6]^{3+},[\mathrm{Cr}(\mathrm{H}_2 \mathrm{O})_6]^{2+},[\mathrm{Fe}(\mathrm{H}_2 \mathrm{O})_6]^{3+},[\mathrm{Ni}(\mathrm{H}_2 \mathrm{O})_6]^{3+},[\mathrm{Cu}(\mathrm{H}_2 \mathrm{O})_6]^{2+}$$ [Given atomic numbers: $$\mathrm{V}=23, \mathrm{Cr}=24, \mathrm{Fe}=26, \mathrm{Ni}=28 \mathrm{Cu}=29$$]

A
1
B
5
C
2
D
4
2
JEE Main 2024 (Online) 4th April Morning Shift
MCQ (Single Correct Answer)
+4
-1

What will be the decreasing order of basic strength of the following conjugate bases? $${ }^{-} \mathrm{OH}, \mathrm{R} \overline{\mathrm{O}}, \mathrm{CH}_3 \mathrm{CO} \overline{\mathrm{O}}, \mathrm{Cl}$$

A
$$\mathrm{C} \overline{\mathrm{I}}>\mathrm{R} \overline{\mathrm{O}}>{ }^{-} \mathrm{OH}>\mathrm{CH}_3 \mathrm{CO} \overline{\mathrm{O}}$$
B
$${ }^{-} \mathrm{OH}>\mathrm{R} \overline{\mathrm{O}}>\mathrm{CH}_3 \mathrm{CO} \overline{\mathrm{O}}>\mathrm{C} \overline{1}$$
C
$$\mathrm{C} \overline{\mathrm{I}}>{ }^{-} \mathrm{OH}>\mathrm{R} \overline{\mathrm{O}}>\mathrm{CH}_3 \mathrm{CO} \bar{O}$$
D
$$\mathrm{R} \overline{\mathrm{O}}>{ }^{-} \mathrm{OH}>\mathrm{CH}_3 \mathrm{CO} \overline{\mathrm{O}}>\mathrm{C} \overline{1}$$
3
JEE Main 2024 (Online) 4th April Morning Shift
MCQ (Single Correct Answer)
+4
-1

Given below are two statements :

Statements I : Acidity of $$\alpha$$-hydrogens of aldehydes and ketones is responsible for Aldol reaction.

Statement II : Reaction between benzaldehyde and ethanal will NOT give Cross - Aldol product.

In the light of the above statements, choose the most appropriate answer from the options given below :

A
Both Statement I and Statement II are incorrect
B
Statement I is correct but Statement II is incorrect
C
Both Statement I and Statement II are correct
D
Statement I is incorrect but Statement II is correct
4
JEE Main 2024 (Online) 4th April Morning Shift
MCQ (Single Correct Answer)
+4
-1

Match List I with List II :

LIST I
Mechanism steps
LIST II
Effect
A. JEE Main 2024 (Online) 4th April Morning Shift Chemistry - Basics of Organic Chemistry Question 19 English 1 I. $$-$$ E effect
B. JEE Main 2024 (Online) 4th April Morning Shift Chemistry - Basics of Organic Chemistry Question 19 English 2 II. $$-$$ R effect
C. JEE Main 2024 (Online) 4th April Morning Shift Chemistry - Basics of Organic Chemistry Question 19 English 3 III. $$+$$ E effect
D. JEE Main 2024 (Online) 4th April Morning Shift Chemistry - Basics of Organic Chemistry Question 19 English 4 IV. $$+$$ R effect

Choose the correct answer from the options given below :

A
(A) - (I), (B) - (II), (C) - (IV), (D) - (III)
B
(A) - (II), (B) - (IV), (C) - (III), (D) - (I)
C
(A) - (III), (B) - (I), (C) - (II), (D) - (IV)
D
(A) - (IV), (B) - (III), (C) - (I), (D) - (II)
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