Match List I with List II

Choose the correct answer from the options given below :

Match List I with List II

Choose the correct answer from the options given below :

Some amount of dichloromethane $$\left(\mathrm{CH}_{2} \mathrm{Cl}_{2}\right)$$ is added to $$671.141 \mathrm{~mL}$$ of chloroform $$\left(\mathrm{CHCl}_{3}\right)$$ to prepare $$2.6 \times 10^{-3} \mathrm{M}$$ solution of $$\mathrm{CH}_{2} \mathrm{Cl}_{2}(\mathrm{DCM})$$. The concentration of $$\mathrm{DCM}$$ is ___________ ppm (by mass).

Given :

atomic mass : C = 12

H = 1

Cl = 35.5

density of $$\mathrm{CHCl}_{3}=1.49 \mathrm{~g} \mathrm{~cm}^{-3}$$

If compound A reacts with B following first order kinetics with rate constant $$2.011 \times 10^{-3} \mathrm{~s}^{-1}$$. The time taken by $$\mathrm{A}$$ (in seconds) to reduce from $$7 \mathrm{~g}$$ to $$2 \mathrm{~g}$$ will be ___________. (Nearest Integer)

$$[\log 5=0.698, \log 7=0.845, \log 2=0.301]$$