The correct order in aqueous medium of basic strength in case of methyl substituted amines is :

Match the List-I with List-II :

Correct match is -

The density of a monobasic strong acid (Molar mass 24.2 g/mol) is 1.21 kg/L. The volume of its solution required for the complete neutralization of 25 mL of 0.24 M NaOH is __________ $$\times$$ 10$$^{-2}$$ mL (Nearest integer)

A litre of buffer solution contains 0.1 mole of each of NH$$_3$$ and NH$$_4$$Cl. On the addition of 0.02 mole of HCl by dissolving gaseous HCl, the pH of the solution is found to be _____________ $$\times$$ 10$$^{-3}$$ (Nearest integer)

[Given : $$\mathrm{pK_b(NH_3)=4.745}$$

$$\mathrm{\log2=0.301}$$

$$\mathrm{\log3=0.477}$$

$$\mathrm{T=298~K]}$$