Given below are two statements : one is labelled as Assertion A and the other is labelled as Reason R :
Assertion A : Acetal / Ketal is stable in basic medium.
Reason R : The high leaving tendency of alkoxide ion gives the stability to acetal/ketal in basic medium.
In the light of the above statements, choose the correct answer from the options given below :
The correct order in aqueous medium of basic strength in case of methyl substituted amines is :
Match the List-I with List-II :
List-I Cations |
List-II Group reagents |
||
---|---|---|---|
A. | $$\mathrm{Pb^{2+},Cu^{2+}}$$ | i) | $$\mathrm{H_2S}$$ gas in presence of dilute HCl |
B. | $$\mathrm{Al^{3+},Fe^{3+}}$$ | ii) | $$\mathrm{(NH_4)_2CO_3}$$ in presence of $$\mathrm{NH_4OH}$$ |
C. | $$\mathrm{Co^{2+},Ni^{2+}}$$ | iii) | $$\mathrm{NH_4OH}$$ in presence of $$\mathrm{NH_4Cl}$$ |
D. | $$\mathrm{Ba^{2+},Ca^{2+}}$$ | iv) | H2S in presence of NH4OH |
Correct match is -
Compound A reacts with NH$$_4$$Cl and forms a compound B. Compound B reacts with H$$_2$$O and excess of CO$$_2$$ to form compound C which on passing through or reaction with saturated NaCl solution forms sodium hydrogen carbonate. Compound A, B and C, are respectively :