$$2 \mathrm{NO}+2 \mathrm{H}_{2} \rightarrow \mathrm{N}_{2}+2 \mathrm{H}_{2} \mathrm{O}$$
The above reaction has been studied at $$800^{\circ} \mathrm{C}$$. The related data are given in the table below
Reaction serial number | Initial Pressure of $${H_2}/kPa$$ | Initial Pressure of $$NO/kPa$$ | Initial rate $$\left( {{{ - dp} \over {dt}}} \right)/(kPa/s)$$ |
---|---|---|---|
1 | 65.6 | 40.0 | 0.135 |
2 | 65.6 | 20.1 | 0.033 |
3 | 38.6 | 65.6 | 0.214 |
4 | 19.2 | 65.6 | 0.106 |
The order of the reaction with respect to NO is ___________.
Amongst the following, the number of oxide(s) which are paramagnetic in nature is
$$\mathrm{Na}_{2} \mathrm{O}, \mathrm{KO}_{2}, \mathrm{NO}_{2}, \mathrm{~N}_{2} \mathrm{O}, \mathrm{ClO}_{2}, \mathrm{NO}, \mathrm{SO}_{2}, \mathrm{Cl}_{2} \mathrm{O}$$
The molar heat capacity for an ideal gas at constant pressure is $$20.785 \mathrm{~J} \mathrm{~K}^{-1} \mathrm{~mol}^{-1}$$. The change in internal energy is $$5000 \mathrm{~J}$$ upon heating it from $$300 \mathrm{~K}$$ to $$500 \mathrm{~K}$$. The number of moles of the gas at constant volume is ____________. [Nearest integer] (Given: $$\mathrm{R}=8.314 \mathrm{~J} \mathrm{~K}^{-1} \mathrm{~mol}^{-1}$$)
According to MO theory, number of species/ions from the following having identical bond order is ________.
$$\mathrm{CN}^{-}, \mathrm{NO}^{+}, \mathrm{O}_{2}, \mathrm{O}_{2}^{+}, \mathrm{O}_{2}^{2+}$$