In Carius method of estimation of halogen, $$0.45 \mathrm{~g}$$ of an organic compound gave $$0.36 \mathrm{~g}$$ of $$\mathrm{AgBr}$$. Find out the percentage of bromine in the compound.

(Molar masses : $$\mathrm{AgBr}=188 \mathrm{~g} \mathrm{~mol}^{-1} ; \mathrm{Br}=80 \mathrm{~g} \mathrm{~mol}^{-1}$$)

Match List I with List II.

Choose the correct answer from the options given below:

$$20 \mathrm{~mL}$$ of $$0.02 \,\mathrm{M} \,\mathrm{K}_{2} \mathrm{Cr}_{2} \mathrm{O}_{7}$$ solution is used for the titration of $$10 \mathrm{~mL}$$ of $$\mathrm{Fe}^{2+}$$ solution in the acidic medium.

The molarity of $$\mathrm{Fe}^{2+}$$ solution is __________ $$\times \,10^{-2}\, \mathrm{M}$$. (Nearest Integer)

$$2 \mathrm{NO}+2 \mathrm{H}_{2} \rightarrow \mathrm{N}_{2}+2 \mathrm{H}_{2} \mathrm{O}$$

The above reaction has been studied at $$800^{\circ} \mathrm{C}$$. The related data are given in the table below

The order of the reaction with respect to NO is ___________.