An organic compound $$'\mathrm{A}'$$ contains nitrogen and chlorine. It dissolves readily in water to give a solution that turns litmus red. Titration of compound $$'\mathrm{A}'$$ with standard base indicates that the molecular weight of $$'\mathrm{A}'$$ is $$131 \pm 2$$. When a sample of $$'\mathrm{A}'$$ is treated with aq. $$\mathrm{NaOH}$$, a liquid separates which contains $$\mathrm{N}$$ but not $$\mathrm{Cl}$$. Treatment of the obtained liquid with nitrous acid followed by phenol gives orange precipitate. The compound $$'\mathrm{A}'$$ is :
Match List - I with Match List - II.
List - I | List - II | ||
---|---|---|---|
(A) | Glucose + HI | (I) | Gluconic acid |
(B) | Glucose + Br$$_2$$ water | (II) | Glucose pentacetate |
(C) | Glucose + acetic anhydride | (III) | Saccharic acid |
(D) | Glucose + HNO$$_3$$ | (IV) | Hexane |
Choose the correct answer from the options given below:
Match List - I with List - II.
List - I (Mixture) |
List - II (Purification Process) |
||
---|---|---|---|
(A) | Chloroform & Aniline | (I) | Steam distillation |
(B) | Benzoic acid & Napthalene | (II) | Sublimation |
(C) | Water & Aniline | (III) | Distillation |
(D) | Napthalene & Sodium chloride | (IV) | Crystallisation |
Choose the correct answer from the options given below :
$$\mathrm{Fe}^{3+}$$ cation gives a prussian blue precipitate on addition of potassium ferrocyanide solution due to the formation of :