1
JEE Main 2019 (Online) 9th January Evening Slot
MCQ (Single Correct Answer)
+4
-1
Change Language
When the first electron gain enthalpy $$\left( {{\Delta _{eg}}H} \right)$$ of oxygen is $$-$$ 141 kJ/mol, its second electron gain enthalpy is :
A
a more negative value than the first
B
almost the same as that of the first
C
negative, but less negative than the first
D
a positive value
2
JEE Main 2019 (Online) 9th January Evening Slot
MCQ (Single Correct Answer)
+4
-1
Change Language
In which of the following process, the bond order has increased and paramagnetic character has charged to diamagnetic ?
A
NO $$ \to $$ NO+
B
N2 $$ \to $$ N2+
C
O2 $$ \to $$ O2+
D
O2 $$ \to $$ O22$$-$$
3
JEE Main 2019 (Online) 9th January Evening Slot
MCQ (Single Correct Answer)
+4
-1
Change Language
Which of the following combination of statements is true regarding the interpretation of the atomic orbitals ?

(a) An electron in an orbital of high angular momentum stays away from the nucleus than an electron in the orbital of lower angular momentum.

(b) For a given value of the principal quantum number, the size of the orbit is inversely proportional to the azimuthal quantum number.

(c) According to wave mechanics, the ground state angular momentum is equal to $${h \over {2\pi }}$$.

(d) The plot of $$\psi $$ vs r for various azimuthal quantum numbers, shows peak shifting towards higher r value.
A
(a), (b)
B
(a), (d)
C
(b), (c)
D
(a), (c)
4
JEE Main 2019 (Online) 9th January Evening Slot
MCQ (Single Correct Answer)
+4
-1
Change Language
For the reaction, 2A + B $$ \to $$ products, when the concentrations of A and B both were doubled, the rate of the reaction increased from 0.3 mol L$$-$$1s$$-$$1 to 2.4 mol L$$-$$1s$$-$$1. When the concentration of A alone is doubled, the rate increased from 0.3 mol L$$-$$1s$$-$$1 to 0.6 mol L$$-$$1s$$-$$1.
A
Total order of the reaction is 4
B
Order of the reaction with respect to B is 2
C
Order of the reaction with respect to B is 1
D
Order of the reaction with respect to A is 2
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