Homoleptic octahedral complexes of a metal ion 'M³⁺' with three monodenate ligands L₁, L₂ and L₃ adsorb wavelenths in the region of green, blue and red respectively. The increasing order of the ligands strength is :

Consider the following reversible chemical reactions :



The relation between K₁ and K₂ is :

The correct match between Item I and Item II is :

Item - I		Item - II
(A)	Benzaldehyde	(P)	Mobile phase
(B)	Alumina	(Q)	Adsorbent
(C)	Acetonitrile	(R)	Adsorbate

The entropy change associated with the conversion of 1 kg of ice at 273 K to water vapours at 383 K is :

(Specific heat of water liquid and water vapour are 4.2 kJ K^$$-$$1 kg^$$-$$1 and 2.0 kJ K^$$-$$1 kg^$$-$$1; heat of liquid fusion and vapourisation of water are 334 kJ^$$-$$1 and 2491 kJ kg^$$-$$1, respectively). (log 273 = 2.436, log 373 = 2.572, log 383 = 2.583)