In which of the following process, the bond order has increased and paramagnetic character has charged to diamagnetic ?

Let z₀ be a root of the quadratic equation, x² + x + 1 = 0, If z = 3 + 6iz$$_0^{81}$$ $$-$$ 3iz$$_0^{93}$$, then arg z is equal to :

If   $$\int\limits_0^{{\pi \over 3}} {{{\tan \theta } \over {\sqrt {2k\,\sec \theta } }}} \,d\theta = 1 - {1 \over {\sqrt 2 }},\left( {k > 0} \right),$$ then value of k is :

The number of natural numbers less than 7,000 which can be formed by using the digits 0, 1, 3, 7, 9 (repitition of digits allowed) is equal to :