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1

AIEEE 2006

MCQ (Single Correct Answer)

+4

-1

Given the data at 25^oC,
Ag + I^- $$\to$$ AgI + e^- , E^o = 0.152 V
Ag $$\to$$ Ag⁺ + e^-, E^o = -0.800 V
What is the value of log K_sp for AgI? (2.303 RT/F = 0.059 V)

A

–8.12

B

+8.612

C

–37.83

D

–16.13

2

AIEEE 2006

MCQ (Single Correct Answer)

+4

-1

The increasing order of stability of the following free radicals is

A

$${({C_6}{H_5})_2}\mathop C\limits^ \bullet H$$ < $${({C_6}{H_5})_3}\mathop C\limits^ \bullet$$ < $${(C{H_3})_3}\mathop C\limits^ \bullet $$ < $${(C{H_3})_2}\mathop C\limits^ \bullet H$$

B

$${(C{H_3})_2}\mathop C\limits^ \bullet H$$ < $${(C{H_3})_3}\mathop C\limits^ \bullet $$ < $${({C_6}{H_5})_2}\mathop C\limits^ \bullet H$$ < $${({C_6}{H_5})_3}\mathop C\limits^ \bullet$$

C

$${(C{H_3})_2}\mathop C\limits^ \bullet H$$ < $${(C{H_3})_3}\mathop C\limits^ \bullet $$ < $${({C_6}{H_5})_3}\mathop C\limits^ \bullet$$ < $${({C_6}{H_5})_2}\mathop C\limits^ \bullet H$$

D

$${({C_6}{H_5})_3}\mathop C\limits^ \bullet$$ < $${({C_6}{H_5})_2}\mathop C\limits^ \bullet H$$ < $${(C{H_3})_3}\mathop C\limits^ \bullet $$ < $${(C{H_3})_2}\mathop C\limits^ \bullet H$$

3

AIEEE 2006

MCQ (Single Correct Answer)

+4

-1

Increasing order of stability among the three main conformations (i.e. Eclipse, Anti, Gauche) of 2-fluoroethanol is

A

Eclipse, Gauche, Anti

B

Gauche, Eclipse, Anti

C

Eclipse, Anti, Gauche

D

Anti, Gauche, Eclipse

4

AIEEE 2006

MCQ (Single Correct Answer)

+4

-1

CH₃Br + Nu^- $$\to$$ CH₃ - Nu + Br^- The decreasing order of the rate of the above reaction with nucleophiles (Nu^–) A to D is
[Nu^– = (A) PhO^–, (B) AcO^–, (C) HO–, (D) CH₃O^–]

A

A > B > C > D

B

B > D > C > A

C

D > C > A > B

D

D > C > B > A

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