1
AIEEE 2006
MCQ (Single Correct Answer)
+4
-1
Phosphorus pentachloride dissociates as follows, in a closed reaction vessel
PCl5 (g) $$\leftrightharpoons$$ PCl3 (g) + Cl2 (g)
If total pressure at equilibrium of the reaction mixture is P and degree of dissociation of PCl5 is x, the partial pressure of PCl3 will be
A
$$\left( {{x \over {x + 1}}} \right)P$$
B
$$\left( {{2x \over {1 - x}}} \right)P$$
C
$$\left( {{x \over {x - 1}}} \right)P$$
D
$$\left( {{x \over {1 - x}}} \right)P$$
2
AIEEE 2006
MCQ (Single Correct Answer)
+4
-1
The equilibrium constant for the reaction
SO3 (g) $$\leftrightharpoons$$ SO2 (g) + $$1 \over 2$$ O2 (g)
is Kc = 4.9 $$\times$$ 10–2. The value of Kc for the reaction
2SO2 (g) + O2 (g) $$\leftrightharpoons$$ 2SO3 (g) will be :
A
416
B
9.8 $$\times$$ 10-2
C
4.9 $$\times$$ 10-2
D
2.40 $$\times$$ 10-3
3
AIEEE 2006
MCQ (Single Correct Answer)
+4
-1
Given the data at 25oC,
Ag + I- $$\to$$ AgI + e- , Eo = 0.152 V
Ag $$\to$$ Ag+ + e-, Eo = -0.800 V
What is the value of log Ksp for AgI? (2.303 RT/F = 0.059 V)
A
–8.12
B
+8.612
C
–37.83
D
–16.13
4
AIEEE 2006
MCQ (Single Correct Answer)
+4
-1
CH3Br + Nu- $$\to$$ CH3 - Nu + Br- The decreasing order of the rate of the above reaction with nucleophiles (Nu) A to D is
[Nu = (A) PhO, (B) AcO, (C) HO–, (D) CH3O]
A
A > B > C > D
B
B > D > C > A
C
D > C > A > B
D
D > C > B > A
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