1
AIEEE 2007
MCQ (Single Correct Answer)
+4
-1
Identify the correct statement regarding a spontaneous process :
A
For a spontaneous process in an isolated system, the change in entropy is positive
B
Endothermic processes are never spontaneous
C
Exothermic processes are always spontaneous
D
Lowering of energy in the reaction process is the only criterion for spontaneity
2
AIEEE 2007
MCQ (Single Correct Answer)
+4
-1
In conversion of lime-stone to lime,
CaCO3(s) $$\to$$ CaO(s) + CO2 (g) the vales of ∆H° and ∆S° are +179.1 kJ mol−1 and 160.2 J/K respectively at 298 K and 1 bar. Assuming that ∆H° do not change with temperature, temperature above which conversion of limestone to lime will be spontaneous is :
A
1008 K
B
1200
C
845 K
D
1118 K
3
AIEEE 2006
MCQ (Single Correct Answer)
+4
-1
The standard enthalpy of formation $$\Delta _fH^o$$ at 298 K for methane, CH4(g), is –74.8 kJ mol–1. The additional information required to determine the average energy for C – H bond formation would be :
A
the dissociation energy of H2 and enthalpy of sublimation of carbon
B
latent heat of vapourization of methane
C
the first four ionization energies of carbon and electron gain enthalpy of hydrogen
D
the dissociation energy of hydrogen molecule, H2
4
AIEEE 2006
MCQ (Single Correct Answer)
+4
-1
The enthalpy changes for the following processes are listed below :

Cl2(g) = 2Cl(g), 242.3 kJ mol–1
I2(g) = 2I(g), 151.0 kJ mol–1
ICl(g) = I(g) + Cl(g), 211.3 kJ mol–1
I2(s) = I2(g), 62.76 kJ mol–1

Given that the standard states for iodine and chlorine are I2(s) and Cl2(g), the standard enthalpy of formation for ICl(g) is :
A
–14.6 kJ mol–1
B
–16.8 kJ mol–1
C
+16.8 kJ mol–1
D
+244.8 kJ mol–1

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