1
AIEEE 2007
MCQ (Single Correct Answer)
+4
-1
Identify the correct statement regarding a spontaneous process :
A
For a spontaneous process in an isolated system, the change in entropy is positive
B
Endothermic processes are never spontaneous
C
Exothermic processes are always spontaneous
D
Lowering of energy in the reaction process is the only criterion for spontaneity
2
AIEEE 2007
MCQ (Single Correct Answer)
+4
-1
In conversion of lime-stone to lime,
CaCO3(s) $$\to$$ CaO(s) + CO2 (g) the vales of ∆H° and ∆S° are +179.1 kJ mol−1 and 160.2 J/K respectively at 298 K and 1 bar. Assuming that ∆H° do not change with temperature, temperature above which conversion of limestone to lime will be spontaneous is :
A
1008 K
B
1200
C
845 K
D
1118 K
3
AIEEE 2006
MCQ (Single Correct Answer)
+4
-1
An ideal gas is allowed to expand both reversibly and irreversibly in an isolated system. If Ti is the initial temperature and Tf is the final temperature, which of the following statements is correct?
A
(Tf)irrev > (Tf)rev
B
(Tf)rev = (Tf)irrev
C
Tf > Ti for reversible process but Tf = Ti for irreversible process
D
Tf = Ti for both reversible and irreversible processes
4
AIEEE 2006
MCQ (Single Correct Answer)
+4
-1
The enthalpy changes for the following processes are listed below :

Cl2(g) = 2Cl(g), 242.3 kJ mol–1
I2(g) = 2I(g), 151.0 kJ mol–1
ICl(g) = I(g) + Cl(g), 211.3 kJ mol–1
I2(s) = I2(g), 62.76 kJ mol–1

Given that the standard states for iodine and chlorine are I2(s) and Cl2(g), the standard enthalpy of formation for ICl(g) is :
A
–14.6 kJ mol–1
B
–16.8 kJ mol–1
C
+16.8 kJ mol–1
D
+244.8 kJ mol–1
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