At 320 K, a gas A₂ is 20% dissociated to A(g). The standard free energy change at 320 K and 1 atm in J mol^-1 is approximately : (R = 8.314 JK^-1 mol^-1; ln2 = 0.693; ln 3 = 1.098)

Which of the following lines correctly show the temperature dependence of equilibrium constant K, for an exothermic reaction?

The combustion of benzene(l) gives CO₂(g) and H₂O(l). Given that heat of combustion of benzene at constant volume is –3263.9 kJ mol^–1 at 25^oC; heat of combustion (in kJ mol^–1) of benzene at constant pressure will be :
(R = 8.314 JK^–1 mol^–1)

$$\Delta $$_fG^o at 500 K for substance 'S' in liquid state and gaseous state are +100.7 kcl mol-¹ and +103 kcal mol^-1, respectively. Vapour pressure of liquid 'S' at 500 K is approximately equal to : ( R = 2 cal K^-1 mol^-1 )