The true statement amongst the following is :

If enthalpy of atomisation for Br₂₍₁₎ is x kJ/mol and bond enthalpy for Br₂ is y kJ/mol, the relation between them :

An ideal gas is allowed to expand form 1 L to 10 L against a constant external pressure of I bar. The work done in kJ is :

Enthalpy of sublimation of iodine is 24 cal g^–1 at 200 ^oC. If specific heat of I₂(s) and l₂ (vap) are 0.055 and 0.031 cal g^–1K ^–1 respectively, then enthalpy of sublimation of iodine at 250 ^oC in cal g^–1 is :