Given below are two statements :
Statement I : A catalyst cannot alter the equilibrium constant $\left(\mathrm{K}_{\mathrm{c}}\right)$ of the reaction, temperature remaining constant.
Statement II : A homogenous catalyst can change the equilibrium composition of a system, temperature remaining constant.
In the light of the above statements, choose the correct answer from the options given below
Consider the following chemical equilibrium of the gas phase reaction at a constant temperature : $\mathrm{A}(\mathrm{g}) \rightleftharpoons \mathrm{B}(\mathrm{g})+\mathrm{C}(\mathrm{g})$
If $p$ being the total pressure, $K_p$ is the pressure equilibrium constant and $\alpha$ is the degree of dissociation, then which of the following is true at equilibrium?
Consider the equilibrium
$$ \mathrm{CO}(\mathrm{g})+3 \mathrm{H}_2(\mathrm{~g}) \rightleftharpoons \mathrm{CH}_4(\mathrm{~g})+\mathrm{H}_2 \mathrm{O}(\mathrm{~g}) $$
If the pressure applied over the system increases by two fold at constant temperature then
(A) Concentration of reactants and products increases.
(B) Equilibrium will shift in forward direction.
(C) Equilibrium constant increases since concentration of products increases.
(D) Equilibrium constant remains unchanged as concentration of reactants and products remain same.
Choose the correct answer from the options given below :
At temperature T, compound $AB_{2(g)}$ dissociates as $AB_{2(g)} \rightleftharpoons AB_{(g)} + \frac{1}{2} B_{2(g)}$ having degree of dissociation $ x $ (small compared to unity). The correct expression for $ x $ in terms of $ K_p $ and $ p $ is: