Identify compound (Z) in the following reaction sequence.

The spin-only magnetic moment value of the ion among $$\mathrm{Ti}^{2+}, \mathrm{V}^{2+}, \mathrm{Co}^{3+}$$ and $$\mathrm{Cr}^{2+}$$, that acts as strong oxidising agent in aqueous solution is _________ BM (Near integer).

(Given atomic numbers : $$\mathrm{Ti}: 22, \mathrm{~V}: 23, \mathrm{Cr}: 24, \mathrm{Co}: 27$$)

The heat of combustion of solid benzoic acid at constant volume is $$-321.30 \mathrm{~kJ}$$ at $$27^{\circ} \mathrm{C}$$. The heat of combustion at constant pressure is $$(-321.30-x \mathrm{R}) \mathrm{~kJ}$$, the value of $$x$$ is __________.

In a borax bead test under hot condition, a metal salt (one from the given) is heated at point B of the flame, resulted in green colour salt bead. The spin-only magnetic moment value of the salt is _______ BM (Nearest integer) [Given atomic number of $$\mathrm{Cu}=29, \mathrm{Ni}=28, \mathrm{Mn}=25, \mathrm{Fe}=26$$]