The following reaction occurs in the Blast furnance where iron ore is reduced to iron metal

$$\mathrm{Fe}_2 \mathrm{O}_{3(s)}+3 \mathrm{CO}_{(g)} \rightleftharpoons \mathrm{Fe}_{(j)}+3 \mathrm{CO}_{2(g)}$$

Using the Le-chatelier's principle, predict which one of the following will not disturb the equilibrium.

Identify compound (Z) in the following reaction sequence.

The spin-only magnetic moment value of the ion among $$\mathrm{Ti}^{2+}, \mathrm{V}^{2+}, \mathrm{Co}^{3+}$$ and $$\mathrm{Cr}^{2+}$$, that acts as strong oxidising agent in aqueous solution is _________ BM (Near integer).

(Given atomic numbers : $$\mathrm{Ti}: 22, \mathrm{~V}: 23, \mathrm{Cr}: 24, \mathrm{Co}: 27$$)

The heat of combustion of solid benzoic acid at constant volume is $$-321.30 \mathrm{~kJ}$$ at $$27^{\circ} \mathrm{C}$$. The heat of combustion at constant pressure is $$(-321.30-x \mathrm{R}) \mathrm{~kJ}$$, the value of $$x$$ is __________.