Given below are two statements : one is labelled as Assertion (A) and the other is labelled as Reason (R).

Assertion (A) : In aqueous solutions $\mathrm{Cr}^{2+}$ is reducing while $\mathrm{Mn}^{3+}$ is oxidising in nature.

Reason (R) : Extra stability to half filled electronic configuration is observed than incompletely filled electronic configuration.

In the light of the above statements, choose the most appropriate answer from the options given below :

The functional group that shows negative resonance effect is :

The number of radial node/s for $3 p$ orbital is :

Which among the followng has highest boiling point?