For the reaction

$$\mathrm{H}_{2} \mathrm{F}_{2}(\mathrm{~g}) \rightarrow \mathrm{H}_{2}(\mathrm{~g})+\mathrm{F}_{2}(\mathrm{~g})$$

$$\Delta U=-59.6 \mathrm{~kJ} \mathrm{~mol}^{-1}$$ at $$27^{\circ} \mathrm{C}$$.

The enthalpy change for the above reaction is ($$-$$) __________ $$\mathrm{kJ} \,\mathrm{mol}^{-1}$$ [nearest integer]

Given: $$\mathrm{R}=8.314 \mathrm{~J} \mathrm{~K}^{-1} \mathrm{~mol}^{-1}$$.

The elevation in boiling point for 1 molal solution of non-volatile solute A is $$3 \mathrm{~K}$$. The depression in freezing point for 2 molal solution of $$\mathrm{A}$$ in the same solvent is 6 $$K$$. The ratio of $$K_{b}$$ and $$K_{f}$$ i.e., $$K_{b} / K_{f}$$ is $$1: X$$. The value of $$X$$ is [nearest integer]

$$20 \mathrm{~mL}$$ of $$0.02\, \mathrm{M}$$ hypo solution is used for the titration of $$10 \mathrm{~mL}$$ of copper sulphate solution, in the presence of excess of KI using starch as an indicator. The molarity of $$\mathrm{Cu}^{2+}$$ is found to be ____________ $$\times 10^{-2} \,\mathrm{M}$$. [nearest integer]

Given : $$2 \,\mathrm{Cu}^{2+}+4 \,\mathrm{I}^{-} \rightarrow \mathrm{Cu}_{2} \mathrm{I}_{2}+\mathrm{I}_{2}$$

$$ \mathrm{I}_{2}+2 \mathrm{~S}_{2} \mathrm{O}_{3}^{2-} \rightarrow 2 \mathrm{I}^{-}+\mathrm{S}_{4} \mathrm{O}_{6}^{2-} $$

The spin-only magnetic moment value of the compound with strongest oxidizing ability among $$\mathrm{MnF}_{4}, \mathrm{MnF}_{3}$$ and $$\mathrm{MnF}_{2}$$ is ____________ B.M. [nearest integer]