In the following reactions sequence, structure of A and B respectively will be :

3 g of acetic acid is added to 250 mL of 0.1 M HCL and the solution made up to 500 mL. To 20 mL of this solutions $${1 \over 2}$$ mL of 5 M NaOH is added. The pH of the solution is __________.

[Given : pKa of acetic acid = 4.75, molar mass of acetic of acid = 60 g/mol, log 3 = 0.4771] Neglect any changes in volume.

Consider the following reactions :

$$NaCl{\rm{ }} + {\rm{ }}{K_2}C{r_2}{O_7} + \mathop {{H_2}S{O_4}}\limits_{(conc.)} $$$$ \to $$ (A) + side products

(A) + NaOH $$ \to $$ (B) + Side products

$$\left( B \right){\rm{ }} + \mathop {{H_2}S{O_4}}\limits_{(dilute)} + {\rm{ }}{H_2}{O_2}$$ $$ \to $$ (C) + Side products

The sum of the total number of atoms in one molecule each of (A) and (B) and (C) is

Two open beakers one containing a solvent and the other containing a mixture of that solvent with a non voltatile solute are together selated in a container. Over time :