For the reaction
2H₂(g) + 2NO(g) $$ \to $$ N₂(g) + 2H₂O(g)
the observed rate expression is, rate = K_f[NO]²[H₂]. The rate expression for the reverse reaction is :

Consider the following reactions :
Which of these reactions are possible ?

The flocculation value of HCl for arsenic sulphide sol.
is 30 m mol L^-1 If H₂SO₄ is used for the flocculatiopn of arsenic sulphide, the amount in grams, of H₂SO₄ in 250 ml required for the above purposed is ______.
(molecular mass of H₂SO₄ = 98 g/mol)

3 g of acetic acid is added to 250 mL of 0.1 M HCL and the solution made up to 500 mL. To 20 mL of this solutions $${1 \over 2}$$ mL of 5 M NaOH is added. The pH of the solution is __________.

[Given : pKa of acetic acid = 4.75, molar mass of acetic of acid = 60 g/mol, log 3 = 0.4771] Neglect any changes in volume.